Two-Dimensional Network Topology in Metal-Organic Framework Design: Coordination Geometry and Properties
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Abstract
Two-dimensional metal-organic frameworks (2D MOFs) have emerged as a fascinating class of crystalline materials that exhibit unique structural properties arising from their distinct network topologies and coordination geometries. This comprehensive review examines the intricate relationship between network topology and material properties in 2D MOF systems, focusing on how coordination geometry influences the overall framework architecture and subsequent functional characteristics. The synthesis strategies for achieving specific topological arrangements are discussed, highlighting the role of ligand design and metal node selection in controlling network dimensionality. The study explores various coordination environments and their impact on electronic, optical, and mechanical properties of 2D MOFs. Furthermore, the applications of these materials in diverse fields including biosensing, energy conversion, and environmental remediation are analyzed through the lens of their topological features. The correlation between structural parameters and performance metrics reveals fundamental design principles for engineering 2D MOFs with tailored properties. Recent advances in computational modeling and experimental characterization techniques have provided deeper insights into structure-property relationships in these materials. This work provides a systematic framework for understanding how topological considerations can guide the rational design of next-generation 2D MOF materials with enhanced functionalities for specific applications.
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